Chemistry Letters p. 829 - 832 (1987)
Update date:2022-07-31
Topics:
Tanikaga, Rikuhei
Hosoya, Ken
Kaji, Aritsune
Enantiomerically pure (2S)-1-arenesulfonyl-2-alkanols (1) were prepared by yeast reduction of 1-arenesulfonyl-3-chloro-2-propanones, followed by epoxydation and alkylation.Reaction of dianions of 1 with aldehydes occurred at the pro(R) position of C(1) to give 1,3-diols, which were converted to (3S)-1-alken-3-ols or (2E,4S)-4-hydroxy-2-alkenenitriles in 100percent e.e.
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(1987)Doi:10.1016/S0040-4039(00)96677-2
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(1986)Doi:10.1002/ardp.19873200605
(1987)