Tetrahedron Letters p. 4533 - 4536 (1987)
Update date:2022-07-30
Topics:
Fournet, Guy
Balme, Genevieve
Gore, Jacques
The catalytic carbopalladation of alkylidenecyclopropanes 1 having in R1 an ω-nucleophilic group leads to cyclic compounds resulting from the attack of either the ?-allyl palladium complex 4 or either the ?-palladium complex 5.This last new process is only observed with delocalized carbon nucleophiles when a five-membered ring can be formed.
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(1957)Doi:10.1039/b815828b
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(1987)
