SYNTHESE VON γ-HYDROXYNITRILEN, γ-BUTYROLACTONEN UND α-METHYLENO-γ-BUTYROLACTONEN AUS EPOXIDEN UND NATRIUM-

DOI: 10.1016/S0040-4039(00)96056-8

Source and publish data:

Tetrahedron Letters p. 2111 - 2114 (1987)

Update date:2022-09-26

Topics: Epoxide Experimental SYNTHESE γ-Butyrolactone

Authors:

Bestmann, Hans Juergen

Schmidt, Martin

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Article abstract of DOI:10.1016/S0040-4039(00)96056-8

The highly nucleophilic ylide-anion of sodium- attacks oxiranes by ring-opening.Depending on the work-up-conditions and the further reactions being employed, γ-hydroxynitriles, γ-butyrolactones or α-methyleno-γ-butyrolactones are obtained from the primary products thus formed.

Full text of DOI:10.1016/S0040-4039(00)96056-8

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