Tetrahedron p. 187 - 192 (1983)
Update date:2022-08-04
Topics:
Bucciarelli, Maria
Forni, Arrigo
Marcaccioli, Sergio
Moretti, Irene
Torre, Giovanni
Oxidation of prochiral sulphonimines (RSO2N = CHAr) with (1S)-(+)-PCA, followed by fractional crystallization of the crude reaction products, provides highly optically-pure N-sulphonyl-3-aryloxaziridines 1H-NMR spectra recorded in the presence of chiral solvent or shift reagent, CD spectra, and the results observed by using them as new chiral oxidizing reagents, are also reported.
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