PREPARATION AND REACTIVITY OF THR PENTAMETHYLCYCLOPENTADIENYL COMPLEXES 5-C6Me5)Ru(PPh3)(L)Cl> (L=CO, ButNC) AND 5-C5Me5)Ru(L)2Cl> (L=ButNC, norbornadiene)

DOI: 10.1016/0022-328X(87)85009-X

Source and publish data:

Journal of Organometallic Chemistry p. 221 - 228 (1987)

Update date:2022-09-26

Topics: Preparation

Authors:

Conroy-Lewis, Fiona M.

Simpson, Stephen J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(87)85009-X

The chloro complexes <(η⁵-C5Me5)Ru(norbornadiene)Cl> (2), <(η⁵-C5Me5)Ru-(Bu^tNC)2Cl> (3), <(η⁵-C5Me5)Ru-(PPh3)(Bu^tNC)Cl> (4) and <(η⁵-C5Me5)Ru(PPh3)-(CO)Cl> (5) have been prepared from <(η⁵-C5Me5)Ru(PPh3)2Cl (1).Reaction of 3-5 with sodium methoxide gave the corresponding hydrides 7-9.All the chloro complexes 1-5 ionise readily in methanol containing NH4PF6 and a donor ligand to give a range of new cations as hexafluorophosphate salts.Treatment of 1 and 4 with NOBF4 gave the dicationic nitrosyls, <(η⁵-C5Me5)Ru(PPh3)2NO>(BF4)2 (12) and <(η⁵-C5Me5)Ru(PPh3)Bu^tNC)NO>(BF4)2 (17), respectively.

Full text of DOI:10.1016/0022-328X(87)85009-X

Products guided by the article

Product name:(C₅(CH₃)5)Ru((CH₃)3CNC)2P(OC₆H₅)3⁽¹⁺⁾*PF₆^(1-)=(C₅(CH₃)5)Ru((CH₃)3CNC)2(P(OC₆H₅)3)PF₆

Cas No:112861-43-5

R&D Labs maybe for 112861-43-5

Daicel Chiral Technologies (China)CO.,LTD

Contact:021-5046-0086*8

Address:Part C, FL 5, the 16th Building, No. 69, XiYa Road, WaiGaoQiao Free Trade Zone, Shanghai, 200131, P.R.China
Shanghai YaXian Chemical Co., Ltd

website:https://www.shyaxianchem.com/

Contact:86-21-59562871

Address:NO.28, Moyu Road, Jiading District ,Shanghai, China
Alway Chem, China

website:http://www.alwaychem.com

Contact:+86-532-8586-4000, 8586-5000

Address:NO.51, TAIPING ROAD, QINGDAO, CHINA. 266001
TIANJIN GST CHEMICAL TECHNOLOGY CO., LTD

Contact:+86-22-25210964

Address:Room. 208, No. -12-C, No. 13, Xinbei Road, Tanggu District, New Haixin Area, Tianjin City, China
Sichuan Mianzhu Ronghong Chemical Co.,LTd

Contact:8613981840544

Address:XINSHI INDUSTRY PARK,MIANZHU,SICHUAN,CHINA

Relevant to this article

Thieme Chemistry Journal awardees - Where are they now? Efforts towards the total synthesis of vinigrol

Doi:10.1055/s-0028-1087378
(2009)
Doi:10.1021/jo01355a014
(1957)
A microwave-assisted stereoselective synthesis of polyandrocarpamines A and B

Doi:10.1016/j.tetlet.2008.12.010
(2009)
Microwave-assisted Sonogashira-type cross couplings of various heterocyclic methylthioethers

Doi:10.1016/j.tetlet.2008.12.055
(2009)
A new route to substituted phenols by cationic rhodium(l)/BINAP complex-catalyzed decarboxylative [2 + 2 + 2] cycloaddition

Doi:10.1021/ol900123d
(2009)
THE EFFECT OF SULFUR AND SELENIUM SUBSTITUTENTS ON THE REGIOCHEMISTRY OF DIELS-ALDER REACTIONS

Doi:10.1016/S0040-4039(00)99054-3
(1985)

Article Doi