PREPARATION AND REACTIVITY OF THR PENTAMETHYLCYCLOPENTADIENYL COMPLEXES 5-C6Me5)Ru(PPh3)(L)Cl> (L=CO, ButNC) AND 5-C5Me5)Ru(L)2Cl> (L=ButNC, norbornadiene)

DOI: 10.1016/0022-328X(87)85009-X

Source and publish data:

Journal of Organometallic Chemistry p. 221 - 228 (1987)

Update date:2022-09-26

Topics: Preparation

Authors:

Conroy-Lewis, Fiona M.

Simpson, Stephen J.

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Article abstract of DOI:10.1016/0022-328X(87)85009-X

The chloro complexes <(η⁵-C5Me5)Ru(norbornadiene)Cl> (2), <(η⁵-C5Me5)Ru-(Bu^tNC)2Cl> (3), <(η⁵-C5Me5)Ru-(PPh3)(Bu^tNC)Cl> (4) and <(η⁵-C5Me5)Ru(PPh3)-(CO)Cl> (5) have been prepared from <(η⁵-C5Me5)Ru(PPh3)2Cl (1).Reaction of 3-5 with sodium methoxide gave the corresponding hydrides 7-9.All the chloro complexes 1-5 ionise readily in methanol containing NH4PF6 and a donor ligand to give a range of new cations as hexafluorophosphate salts.Treatment of 1 and 4 with NOBF4 gave the dicationic nitrosyls, <(η⁵-C5Me5)Ru(PPh3)2NO>(BF4)2 (12) and <(η⁵-C5Me5)Ru(PPh3)Bu^tNC)NO>(BF4)2 (17), respectively.

Full text of DOI:10.1016/0022-328X(87)85009-X

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