Journal of Organometallic Chemistry p. 221 - 228 (1987)
Update date:2022-09-26
Topics: Preparation
Conroy-Lewis, Fiona M.
Simpson, Stephen J.
The chloro complexes <(η5-C5Me5)Ru(norbornadiene)Cl> (2), <(η5-C5Me5)Ru-(ButNC)2Cl> (3), <(η5-C5Me5)Ru-(PPh3)(ButNC)Cl> (4) and <(η5-C5Me5)Ru(PPh3)-(CO)Cl> (5) have been prepared from <(η5-C5Me5)Ru(PPh3)2Cl (1).Reaction of 3-5 with sodium methoxide gave the corresponding hydrides 7-9.All the chloro complexes 1-5 ionise readily in methanol containing NH4PF6 and a donor ligand to give a range of new cations as hexafluorophosphate salts.Treatment of 1 and 4 with NOBF4 gave the dicationic nitrosyls, <(η5-C5Me5)Ru(PPh3)2NO>(BF4)2 (12) and <(η5-C5Me5)Ru(PPh3)ButNC)NO>(BF4)2 (17), respectively.
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(1985)
