Tetrahedron Letters p. 4479 - 4482 (1997)
Update date:2022-08-04
Topics:
Yadav
Barma
Dutta, Dinah
An efficient protocol for the synthesis of chiral polyhydroxy-(E, E)-1-chlorodienols and (E)-5-hydroxy enynes from chiral 4,5-epoxy trans allyl chlorides and 4,5-O-isopropylidene allyl chlorides is described by using stoichiometric amount of LiNH2 or LDA in HMPA : THF (1 : 5) useful in the synthesis of biologically active natural products.
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