A highly efficient practical method for the synthesis of chiral polyhydroxy-(E,E)-1-chlorodienols and (E)-5-hydroxy enynes

DOI: 10.1016/S0040-4039(97)00907-6

Source and publish data:

Tetrahedron Letters p. 4479 - 4482 (1997)

Update date:2022-08-04

Topics:

Authors:

Yadav Yadav

Barma Barma

Dutta, Dinah

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Article abstract of DOI:10.1016/S0040-4039(97)00907-6

An efficient protocol for the synthesis of chiral polyhydroxy-(E, E)-1-chlorodienols and (E)-5-hydroxy enynes from chiral 4,5-epoxy trans allyl chlorides and 4,5-O-isopropylidene allyl chlorides is described by using stoichiometric amount of LiNH₂ or LDA in HMPA : THF (1 : 5) useful in the synthesis of biologically active natural products.

Full text of DOI:10.1016/S0040-4039(97)00907-6

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