DIASTEREOSELECTIVE ELABORATION OF THE CARBON SKELETON OF β-HYDROXYESTERS FROM YEAST REDUCTIONS PREPARATION OF (2S)-2-HYDROXY-CYCLOHEXANE CARBOXYLIC ACIDS WITH THREE CONTIGUOUS STEREOGENIC CENTERS

DOI: 10.1016/S0040-4039(00)96385-8

Source and publish data:

Tetrahedron Letters p. 3791 - 3794 (1987)

Update date:2022-09-26

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Authors:

Seebach, Dieter

Herradon, Bernardo

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Article abstract of DOI:10.1016/S0040-4039(00)96385-8

The dioxanone-type acetal 2 from (1R,2S)-2-hydroxy-cyclo-hexane carboxylic acid (1) and pivalaldehyde is dehydrogenated to a derivative 3 of 6-hydroxy-cyclohexene carboxylic acid.Highly selective Michael additions and trapping of the resulting enolates wi

Full text of DOI:10.1016/S0040-4039(00)96385-8

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