Journal of the American Chemical Society p. 8223 - 8227 (1986)
Update date:2022-08-04
Topics:
Harman, W. Dean
Fairlie, David P.
Taube, Henry
When a novel (η2-acetone)pentaammine complex is formed which shows markedly different reactivity from the ruthenium analogue.The crystal structure has been determined and C-O, Os-O, and Os-C bond lengths are found to be 1.32, 2.06,and 2.13 Angstroem, respectively.The ν(C-O) has been assigned by isotopic labeling to be 1330 cm-1.
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