Synthesis, Characterization, and Reactivity of the (η2-Acetone)pentaammineosmiun(II) Complex

DOI: 10.1021/ja00286a018

Source and publish data:

Journal of the American Chemical Society p. 8223 - 8227 (1986)

Update date:2022-08-04

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Authors:

Harman, W. Dean

Fairlie, David P.

Taube, Henry

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Article abstract of DOI:10.1021/ja00286a018

When ²⁺ is reduced in acetone a novel (η²-acetone)pentaammine complex is formed which shows markedly different reactivity from the ruthenium analogue.The crystal structure has been determined and C-O, Os-O, and Os-C bond lengths are found to be 1.32, 2.06,and 2.13 Angstroem, respectively.The ν(C-O) has been assigned by isotopic labeling to be 1330 cm^-1.

Full text of DOI:10.1021/ja00286a018

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