Insertion of carbon disulfide into ruthenium-alkenyl bonds. Formation of an alkenedithiocarboxylate ligand

DOI: 10.1021/om00095a033

Source and publish data:

Organometallics p. 1223 - 1224 (1988)

Update date:2022-09-26

Topics:

Authors:

Torres, M. Rosario

Perales, Aurea

Ros, Josep

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Article abstract of DOI:10.1021/om00095a033

CS₂ reacts with complexes Ru(CO)Cl(HC= CHR)(PPh₃)₂ (R = Ph or t-Bu) to give products Ru(CO)-Cl(S₂C(H)C=CHR)(PPh₃)₂ (R = Ph (1) and t-Bu (2)). The insertion products contain an alkenedithioc

Full text of DOI:10.1021/om00095a033

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Product name:Ru(CO)Cl(S₂CHCCHC₆H₅)(P(C₆H₅)3)2

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