Journal of the Chemical Society. Chemical communications p. 230 - 231 (1987)
Update date:2022-08-04
Topics:
Khasnis, Dilip V.
Toupet, Loic
Dixneuf, Pierre H.
Reaction of Fe(X)(η2-CS2R)(CO)(PR3)2 (X=Cl, I) complexwes with NaBH4 leads to both hydride and BH3 additions with the formation of dithioformate-iron(0)Fe<η3-HC(SR)S BH3>(CO)(PR3)2 complexes (4) containing an agostic B-H-Fe interaction; the addition of pyridine to (4) liberates a 16 electron-iron(0) moiety by trapping of the BH3 unit.
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Doi:10.1002/anie.201404432
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