OVERRIDING NORMAL FRIEDEL-CRAFTS REGIOCHEMISTRY IN CYCLIACYLATION. REGIOSPECIFIC CARBODESILYLATION AND PARHAM CYCLIZATION ROUTES TO 7-METHOXY-1-INDANOLS

DOI: 10.1016/S0040-4039(00)96247-6

Source and publish data:

Tetrahedron Letters p. 2933 - 2936 (1987)

Update date:2022-08-03

Topics:

Authors:

Sibi, M. P.

Shankaran, K.

Alo, B. I.

Hahn, W. R.

Snieckus, V.

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Article abstract of DOI:10.1016/S0040-4039(00)96247-6

Regiospecific syntheses of 7-methoxy-1-indanols (11a-c) and indanones (13a-c) via fluoride-induced carbodesilylation and Parham cyclization processes respectively are reported.

Full text of DOI:10.1016/S0040-4039(00)96247-6

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