Bulletin of the Chemical Society of Japan p. 3431 - 3432 (1987)
Update date:2022-08-05
Topics: Allylic Alkylation Liquid Phase
Masuyama, Yoshiro
Mitsunaga, Yutaka
Kurusu, Yasuhiko
Segawa, Koh-ichi
Titanium oxide-supported carbonylmolybdenum catalyst was applied to selective monoallylation of methyl p-tolylsulfonylacetate using allylic acetates or carbonates in refluxing dioxane.This reaction required both 2,2'-bipyridyl as a ligind and sodium hydride as a base for preparation of the salt of methyl p-tolylsulfonylacetate.
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(1993)Doi:10.1021/ja00216a061
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(1988)
