Titanium Oxide-Supported Carbonylmolybdenum Catalyst in Liquid Phase: Application to Allylic Alkylation of Methyl p-Tolylsulfonylacetate

DOI: 10.1246/bcsj.60.3431

Source and publish data:

Bulletin of the Chemical Society of Japan p. 3431 - 3432 (1987)

Update date:2022-08-05

Topics: Allylic Alkylation Liquid Phase

Authors:

Masuyama, Yoshiro

Mitsunaga, Yutaka

Kurusu, Yasuhiko

Segawa, Koh-ichi

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Article abstract of DOI:10.1246/bcsj.60.3431

Titanium oxide-supported carbonylmolybdenum catalyst was applied to selective monoallylation of methyl p-tolylsulfonylacetate using allylic acetates or carbonates in refluxing dioxane.This reaction required both 2,2'-bipyridyl as a ligind and sodium hydride as a base for preparation of the salt of methyl p-tolylsulfonylacetate.

Full text of DOI:10.1246/bcsj.60.3431

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