Journal of the Chemical Society. Perkin transactions II p. 1 - 6 (1988)
Update date:2022-07-29
Topics:
Fahmy, Hussein M.
Fattah, Nahed F. Abdel
Elmoghayar, Mohamed R. H.
Azzem, Magdy Abdel
The electrochemical reduction of a series of 1,3,4-thiadiazoles in alcoholic buffered media has been investigated.The mechanism of the electrode processes is suggested and discussed.A cyclopentene carboxylic acid product is formed through a Ziegler-Throp reaction; the thiadiazole ring is inactive.Confirmation of the mechanism via c.p.e., spectrophotometric analyses, and the study of Hammett's relations is presented.
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