Cycloaddition Reactions of α-Keto Imines. Regio- and Stereoselectivities in the Dienic and Dienophilic Additions to Conjugated Dienes

DOI: 10.1021/jo00245a023

Source and publish data:

Journal of Organic Chemistry p. 2251 - 2258 (1988)

Update date:2022-09-26

Topics:

Authors:

Lucchini, Vittorio

Prato, Maurizio

Scorrano, Gianfranco

Tecilla, Paolo

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Article abstract of DOI:10.1021/jo00245a023

The α-keto imines 4 or their methanol adducts 5 (a, R = NO2; b, R = Cl; c, R = CH3; d, R = OCH3) add at room temperature under Lewis acid catalysis to 1,3-butadiene, 2-methyl-1,3-butadiene, 2,3-dimethyl-1,3-butadiene, cyclopentadiene, and 1,3-cyclohexadie

Full text of DOI:10.1021/jo00245a023

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