Cycloaddition Reactions of α-Keto Imines. Regio- and Stereoselectivities in the Dienic and Dienophilic Additions to Conjugated Dienes

DOI: 10.1021/jo00245a023

Source and publish data:

Journal of Organic Chemistry p. 2251 - 2258 (1988)

Update date:2022-09-26

Topics:

Authors:

Lucchini, Vittorio

Prato, Maurizio

Scorrano, Gianfranco

Tecilla, Paolo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00245a023

The α-keto imines 4 or their methanol adducts 5 (a, R = NO2; b, R = Cl; c, R = CH3; d, R = OCH3) add at room temperature under Lewis acid catalysis to 1,3-butadiene, 2-methyl-1,3-butadiene, 2,3-dimethyl-1,3-butadiene, cyclopentadiene, and 1,3-cyclohexadie

Full text of DOI:10.1021/jo00245a023

Products guided by the article

Product name:3-Furanamine, 5-ethenyltetrahydro-2-methoxy-5-methyl-N-(4-nitrophenyl)-2-phenyl-

Cas No:113628-37-8

R&D Labs maybe for 113628-37-8

Beijing Top Science biological technology co., LTD

Contact:+86-13439059536

Address:15-1705 jre three mile, Beijing 100000,CHINA
Xinyanhe Pharmatech Co.,Ltd

Contact:+86-519-8525-2752

Address:Changzhou
Nanjing Duly Biotech Co., Ltd

website:http://www.dulynet.com/

Contact:025-84699383 -8003

Address:Room 503, Building 2, Chuangxinhui, No. 61 Wenjing Road, High-tech Development Zone, Pukou District, Nanjing City, Jiangsu Province Nanjing, Jiangsu
Springchem New Material Technology Co.,Limited

website:http://www.spring-chem.com

Contact:86-21-62885108

Address:602B, Building 1, No. 641, Tianshan Road
KangZhiYuan Pharmaceutical Company Limited

Contact:(Sabrina)86-20-85273232

Address:4th floor, building B, Dadi industry zone, Tangxia, Tianhe, Guangzhou, China

Relevant to this article

Synthesis and chemical properties of 1,3-dichloro-1,3-dihydridodisilazanes

Doi:10.1016/0022-328X(94)85021-6
(1994)
Efficient and scalable total synthesis of calcitroic acid and its ¹³C-labeled derivative

Doi:10.1039/c4ra04322g
(2014)
Fluorescence reagents. I. Derivatization of carboxylic acids, imides and alcohols with 1-chloromethylbenz[c,d]indol-2(1H)-one (CMBI)

Doi:10.1002/jhet.5570240531
(1987)
Iron/palladium-catalyzed intramolecular hydroamination: An expedient synthesis of pyrrole-annulated coumarin and quinolone derivatives

Doi:10.1055/s-0030-1258311
(2010)
Crystal structures and spectral studies of [Ph₃Sn(O ₂AsMe₂)], [Bu₂ClSn(O₂AsMe ₂)] and [PhClSn(O₂AsMe₂)(μ-OMe)]₂

Doi:10.1002/zaac.200700415
(2008)
Synthesis, characterization and reactivity of a η¹- methylphosphaalkyne complex, [RuH(dppe)₂(η¹- P≡CMe)][CF₃SO₃]

Doi:10.1002/ejic.200701330
(2008)

Article Doi