Diastereoselective Alkylation Guided by Electrophile-Nucleophile ?-Interactions

DOI: 10.1021/jo00244a019

Source and publish data:

Journal of Organic Chemistry p. 1947 - 1952 (1988)

Update date:2022-09-26

Topics:

Authors:

McIntosh, John M.

Leavitt, Randy K.

Mishra, Pratibha

Cassidy, Kenneth C.

Drake, John E.

Chadha, R.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00244a019

Alkylation of the enolate 1a obtained from the (R)-camphor imine of tert-butyl glycinate with a variety of alkylating agents gives products whose trends in diastereomeric excesses appear to correlate with ? electron density and steric effects in the elect

Full text of DOI:10.1021/jo00244a019

Products guided by the article

Product name:3-(4-Nitro-phenyl)-2-[(1R,4R)-1,7,7-trimethyl-bicyclo[2.2.1]hept-(2E)-ylideneamino]-propionic acid tert-butyl ester

Cas No:113647-28-2

R&D Labs maybe for 113647-28-2

HUANGSHAN CICOSINE CHEMICAL S & T CO.,LTD

website:http://www.cicosine.com

Contact:86-559-2328599

Address:Add:B635 New Town Times Building,Tunxi District,Huangshan City
Hebei Kangtai Pharmaceutical Co.,Ltd

Contact:+86-0317-3512963

Address:Wugang Road,Mengcun of Cangzhou City,Hebei Province ,China
NanJing Rate Biochemicals CO., LTD

Contact:+86-25-84931986

Address:NO. 1 Hongjing Road,Jiangning Science Park,Nanjing,China
Jiangsu Institute of Ecomones Co., Ltd

website:http://www.jsmone.com

Contact:+86-519-82821700

Address:95 Huanyuan N. Road, Jintan, Jiangsu, China
Ring Specialty Chemicals Inc.

Contact:+1-416-493-6870

Address:Toronto, Canada

Relevant to this article

Solvent effects on electron delocalization in paramagnetic organometallic complexes: Solvent manipulation of the amount of 19-electron character in Co(CO)₃L₂ (L₂ = a chelating phosphine)

Doi:10.1021/ja00042a019
(1992)
New structural motifs of silver and gold complexes of pyridine-functionalized benzimidazolylidene ligands

Doi:10.1016/j.jorganchem.2009.03.031
(2009)
Synthesis of novel cyclobutylphosphonic acids as inhibitors of imidazole glycerol phosphate dehydratase

Doi:10.1016/S0040-4020(97)00682-0
(1997)
A ferromagnetic chain of imidazolato-bridged one-dimensional copper(ii) complex

Doi:10.1246/bcsj.82.467
(2009)
Halogen dance and sequential cross-coupling on 2-anilinothiazoles

Doi:10.2174/157017809787582780
(2009)
Regiospecific and stereoselective syntheses of (±) morphine, codeine, and thebaine via a highly stereocontrolled intramolecular 4 + 2 cycloaddition leading to a phenanthrofuran system

Doi:10.1021/ja9038505
(2009)

Article Doi