OXIDATION OF ENOL ETHERS BY METAL(VI)OXIDE DIPEROXIDES

DOI: 10.1016/0040-4039(88)85108-6

Source and publish data:

Tetrahedron Letters p. 3145 - 3148 (1988)

Update date:2022-07-29

Topics:

Authors:

Curci, Ruggero

Lopez, Luigi

Troisi, Luigino

Rashid, S. M. Khaledur

Schaap, A. Paul

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Article abstract of DOI:10.1016/0040-4039(88)85108-6

Alkoxy(aryl) adamantylidenes react with chromium(VI) or molybdenum(VI) oxide diperoxides in CHCl3 under argon yielding the corresponding 1,2-dioxetanes and/or carbonyl products derived from the fragmentation of the dioxetanes.The reaction most likely proceeds via preliminary epoxidation of the unsaturated substrates.

Full text of DOI:10.1016/0040-4039(88)85108-6

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