OXIDATION OF ENOL ETHERS BY METAL(VI)OXIDE DIPEROXIDES

DOI: 10.1016/0040-4039(88)85108-6

Source and publish data:

Tetrahedron Letters p. 3145 - 3148 (1988)

Update date:2022-07-29

Topics:

Authors:

Curci, Ruggero

Lopez, Luigi

Troisi, Luigino

Rashid, S. M. Khaledur

Schaap, A. Paul

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(88)85108-6

Alkoxy(aryl) adamantylidenes react with chromium(VI) or molybdenum(VI) oxide diperoxides in CHCl3 under argon yielding the corresponding 1,2-dioxetanes and/or carbonyl products derived from the fragmentation of the dioxetanes.The reaction most likely proceeds via preliminary epoxidation of the unsaturated substrates.

Full text of DOI:10.1016/0040-4039(88)85108-6

Products guided by the article

Product name:4-methoxy-(1-<1-naphthyl>)spiro<1,2-dioxetane-3,2'-adamantane>

Cas No:113849-82-4

R&D Labs maybe for 113849-82-4

Shaanxi Lighte Optoelectronics Material Co., Ltd.

Contact:+86-29-88320728-622/619/620

Address:No.55 INDUSTRY ROAD 2,XI'AN NATIONAL CIVIL AEROSPACE INDUSTRIAL PARK.XI'AN China 710065.
Jiangsu Cale New Material Co.ltd

Contact:+86-515-88334667/88203550

Address:Zhongshan 3rd Road, Coastal Chemical Industry Park, Yancheng, Jiangsu, China
Langchem

Contact:+86+21-58956006 15800617331

Address:402 Room, 150# Cailun Road, Zhangjiang high tech park, Shanghai
Frapp's Chemical (NFTZ) Co.,Ltd

Contact:+86-576-86137892

Address:General Chamber of Commercial Building, 159 Wanchang Middle Road, Wenling, Zhejiang, China
Jinzhou Jiutai Pharmaceutical Co.,Ltd

Contact:+86-0416-5179890

Address:No.41, Taianli, Taihe District, Jinzhou, Liaoning

Relevant to this article

DIFFERENT ROTAMETER POPULATIONS AROUND THE C-5-C-6 BOND FOR α-AND β-D-GALACTOPYRANOSIDES THROUGH THE COMBINED INTERACTION OF THE GAUCH AND ANOMERIC EFFECTS: A 300-MHz ¹H-N.M.R. AND MNDO STUDY

Doi:10.1016/0008-6215(87)80072-1
(1987)
SYNTHETIC 6-GLUCOSYL PHOSPHOLIPID AS A DRUG TRANSPORT SYSTEM

Doi:10.1016/S0040-4039(00)95541-2
(1987)
The face selectivity directed by an allylic group of a diene in the diels-alder reaction is reversed from that of a dienophile

Doi:10.1016/S0040-4039(00)98148-6
(1985)
Determination of bupivacaine in human fetal and neonatal blood samples by quantitative single ion monitoring.

Doi:10.1002/bms.1200040509
(1977)
Formation of a Novel Acyl Anion Equivalent by the Electroreduction of Oxazolinium Salts

Doi:10.1246/cl.1987.1511
(1987)
New Type of 1,3-Molecular Rearrangement of Substituted-Vinyl Alkoxymethyl Ethers and Its Application to Synthesis of 1(or 3)-Substituted 4-Alkoxybutan-2-ones

Doi:10.1021/jo00247a015
(1988)

Article Doi