Catalyzed Reaction of Diazodiphenylethanone and Related Diazo Ketones with Enaminones as a Source of Pyrroles

DOI: 10.1021/jo00244a042

Source and publish data:

Journal of Organic Chemistry p. 2084 - 2086 (1988)

Update date:2022-09-26

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Authors:

Eberlin, Marcos N.

Kascheres, Concetta

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Article abstract of DOI:10.1021/jo00244a042

The reaction of copper(II)-stabilized keto carbenes (1, 7, 8), derived from diazo ketones, with enaminones leads to the formation of pyrroles.The cyclic enaminones 3 react with the keto carbenes on nitrogen to form products 5, 9, 11, and/or pyrroles 6, 10

Full text of DOI:10.1021/jo00244a042

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