Catalyzed Reaction of Diazodiphenylethanone and Related Diazo Ketones with Enaminones as a Source of Pyrroles

DOI: 10.1021/jo00244a042

Source and publish data:

Journal of Organic Chemistry p. 2084 - 2086 (1988)

Update date:2022-09-26

Topics:

Authors:

Eberlin, Marcos N.

Kascheres, Concetta

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00244a042

The reaction of copper(II)-stabilized keto carbenes (1, 7, 8), derived from diazo ketones, with enaminones leads to the formation of pyrroles.The cyclic enaminones 3 react with the keto carbenes on nitrogen to form products 5, 9, 11, and/or pyrroles 6, 10

Full text of DOI:10.1021/jo00244a042

Products guided by the article

Product name:2-Cyclopenten-1-one, 3-[(2-oxo-1,2-diphenylethyl)amino]-

Cas No:113859-87-3

R&D Labs maybe for 113859-87-3

Shanghai united Scientific Co.,Ltd.

Contact:+86-21-53535353

Address:28F No.900 huaihai Road Shanghai China
Shanghai Maxchemco Chemical Industry Co., Ltd.

Contact:(86)21-51079223

Address:No.1305-8, B241, the Ecust Park, Huajing Road, Xuhui District, Shanghai
HuiFeiChem PharmaTech Co.Ltd

Contact:0510-85393305

Address:1619 Huishan Avenue, Huishan District, Wuxi,
Jiangsu Dacheng Pharmaceutical and Chemical Co.,Ltd

Contact:+86-0517-87036900

Address:Chuzhou Chemical park, Huai'an, Jiangsu Province
Jinhua Haoyuan Chemical CO., LTD(expird)

Contact:86-579-82465583

Address:Jinhua,Zhejiang

Relevant to this article

Iron/palladium-catalyzed intramolecular hydroamination: An expedient synthesis of pyrrole-annulated coumarin and quinolone derivatives

Doi:10.1055/s-0030-1258311
(2010)
Crystal structures and spectral studies of [Ph₃Sn(O ₂AsMe₂)], [Bu₂ClSn(O₂AsMe ₂)] and [PhClSn(O₂AsMe₂)(μ-OMe)]₂

Doi:10.1002/zaac.200700415
(2008)
Synthesis, characterization and reactivity of a η¹- methylphosphaalkyne complex, [RuH(dppe)₂(η¹- P≡CMe)][CF₃SO₃]

Doi:10.1002/ejic.200701330
(2008)
Stereoselective synthesis of fully protected (2S,4S,6S)-2-amino-6-hydroxy-4-methyl-8-oxodecanoic acid (AHMOD)

Doi:10.1002/psc.1433
(2012)
Formation and Decomposition of Iron-Carbon ?-Bonds in the Reaction of Iron(II)-Poly(amino carboxylate) Complexes with CO2^- Free Radicals. A Pulse Radiolysis Study

Doi:10.1021/ja00220a030
(1988)
Potential DNA bis-intercalating agents: Synthesis and antitumor activity of novel, conformationally restricted bis(9-aminoacridines)

Doi:10.1002/jhet.5570240535
(1987)

Article Doi