A General Procedure for the Selective Oxidation of Sulfides to Sulfoxides by Nitric Acid: Tetrabromoaurate(III) Catalyst in a Biphasic System

DOI: 10.1021/jo00291a043

Source and publish data:

Journal of Organic Chemistry p. 1323 - 1328 (1990)

Update date:2022-07-29

Topics:

Authors:

Gasparrini, Francesco

Giovannoli, Mario

Misiti, Domenico

Natile, Giovanni

Palmieri, Gianni

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00291a043

Tetrabromoaurate(III) is an efficient catalyst for the oxidation of sulfides to sulfoxides by nitric acid in a biphasic system (nitromethane/water).The system is selective and can be applied to the oxidation of any type of dialkyl and alkyl aryl sulfide and also of diaryl sulfides activated by electron-releasing substituents.The nature of the active species has been investigated in relation to the mechanistic aspects.

Full text of DOI:10.1021/jo00291a043

Products guided by the article

Product name:Benzene, (octadecylsulfinyl)-

Cas No:114045-22-6

R&D Labs maybe for 114045-22-6

JADECHEM NINGBO CO.,LTD.

Contact:+86-574-89075960

Address:#100 Xiang Yun Road, New High tech area, Ningbo, China
Lanzhou huibang biological chemical technology Co., LTD

Contact:0931-7843964

Address:NO.2011,Yannan Road,Chengguan,
Zhenjiang Huayu I/E Co.,LTD

Contact:86-511-85210668 0511-85210668, 85210818, 85210898

Address:Yihai Garden E-902,NO.99 Daxi RD., Zhenjiang Jiiangsu ,China
Shanghai Forever Synthesis Co.,Ltd.

Contact:021-61124658

Address:Zhoukang Road,Pudong New District,Shanghai,China
SHANDONG CREDAGRI CHEMICAL CO., LTD.

Contact:+86-531-88872050

Address:ROOM 601A, BUILDING 2, SHUNTAI SQUARE, NO. 2000 SHUNHUA ROAD, HI-TECH DEVELOPMENT ZONE, JINAN, CHINA.

Relevant to this article

Reductive activation of tripod metal compounds: Identification of intermediates and preparative application

Doi:10.1002/ejic.200700873
(2008)
New Molybdenocene Dihydrocarbyls

Doi:10.1016/S0022-328X(00)99758-4
(1987)
2-Aminoethanesulfonic acid: An efficient organocatalyst for green synthesis of spirooxindole dihydroquinazolinones and novel 1,2-(dihydroquinazolin-3(4H)isonicotinamides in water

Doi:10.1080/00397911.2019.1692868
(2020)
Facile access of well-defined stable divalent lead compounds with small organic substituents

Doi:10.1021/om801167c
(2009)
HIGH- AND ATMOSPHERIC-PRESSURE CYCLOADDITION OF TRICHLOROACETYL ISOCYANATE TO 3,4-DI-O-ACETYL-L-RHAMNAL

Doi:10.1016/S0040-4020(01)86897-6
(1987)
1-Methyl-4-phenyl-1,2,3,6-tetrahydropyridine Analogues. Inactivation of Monoamine Oxidase by Conformationally Rigid Analogues of N,N-Dimethylcinnamylamine

Doi:10.1021/jm00403a013
(1988)

Article Doi