Asymmetric Synthesis of the Spiroacetal Fragment of Milbemycin E

DOI: 10.1039/c39870000877

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 877 - 880 (1987)

Update date:2022-08-04

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Authors:

Khandekar, Girish

Robinson, Gareth C.

Stacey, Nicholas A.

Steel, Patrick G.

Thomas, Eric J.

Vather, Sunil

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Article abstract of DOI:10.1039/c39870000877

Spiro-acetals (17) and (21) have been synthesized from methyl α-D-glucopyranoside (11), via the 6-chloro-4,6-dideoxygalactopyranoside (10), the epoxy-dithiane (8), and the open-chain dithianes (16) and (20).

Full text of DOI:10.1039/c39870000877

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