Tetrahedron Letters p. 4081 - 4084 (1987)
Update date:2022-07-29
Topics:
Kira, Mitsuo
Kobayashi, Mineo
Sakurai, Hideki
Allyltrifluorosilane/CsF systems form pentacoordinate allylsiliconates which undergo chemoselective, regiospecific and highly stereoselective allylation of aldehydes, presumably via six-membered cyclic transition states.
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