REGIOSPECIFIC AND HIGHLY STEREOSELECTIVE ALLYLATION OF ALDEHYDES WITH ALLYLTRIFLUOROSILANE ACTIVATED BY FLUORIDE IONS.

DOI: 10.1016/S0040-4039(01)83867-3

Source and publish data:

Tetrahedron Letters p. 4081 - 4084 (1987)

Update date:2022-07-29

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Authors:

Kira, Mitsuo

Kobayashi, Mineo

Sakurai, Hideki

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Article abstract of DOI:10.1016/S0040-4039(01)83867-3

Allyltrifluorosilane/CsF systems form pentacoordinate allylsiliconates which undergo chemoselective, regiospecific and highly stereoselective allylation of aldehydes, presumably via six-membered cyclic transition states.

Full text of DOI:10.1016/S0040-4039(01)83867-3

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