Chemistry Letters p. 1905 - 1906 (1987)
Update date:2022-08-03
Topics:
Takano, Seiichi
Sekiguchi, Yoshinori
Shimazaki, Youchi
Takahashi, Michiyasu
Ogasawara, Kunio
Optically active terminal-β,γ-acetylenic alcohol rearranges to β-trideuteriomethyl-α,β-acetylenic alcohol, an useful chiral building block for the synthesis of a variety of natural products, on exposure to potassium t-butoxide in dimethyl sulfoxide-d6.
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