1,7-Methanohomopentaprismane: A Propellane

DOI: 10.1021/jo00246a061

Source and publish data:

Journal of Organic Chemistry p. 2662 - 2664 (1988)

Update date:2022-08-02

Topics:

Authors:

Majerski, Zdenko

Veljkovic, Jelena

Kaselj, Mira

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Article abstract of DOI:10.1021/jo00246a061

The intramolecular cycloaddition of 11-methylene-8-pentacyclo<5.4.0.0^2,6.0^3,10.0^5,9>undecanylidene to the olefinic bond leads to 1,7-methanohomopentaprismane, a highly elusive <2.2.1>propellane, which spontaneously abstracts two hydrogen atoms from its environment, yielding 1,3-bishomopentaprismane.

Full text of DOI:10.1021/jo00246a061

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Product name:(3aS,6aR,7aS)-3-Methylene-3a,6a,7,7a-tetrahydro-3H-cyclopenta[a]pentalene

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