1,7-Methanohomopentaprismane: A Propellane

DOI: 10.1021/jo00246a061

Source and publish data:

Journal of Organic Chemistry p. 2662 - 2664 (1988)

Update date:2022-08-02

Topics:

Authors:

Majerski, Zdenko

Veljkovic, Jelena

Kaselj, Mira

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00246a061

The intramolecular cycloaddition of 11-methylene-8-pentacyclo<5.4.0.0^2,6.0^3,10.0^5,9>undecanylidene to the olefinic bond leads to 1,7-methanohomopentaprismane, a highly elusive <2.2.1>propellane, which spontaneously abstracts two hydrogen atoms from its environment, yielding 1,3-bishomopentaprismane.

Full text of DOI:10.1021/jo00246a061

Products guided by the article

Product name:(3aS,6aR,7aS)-3-Methylene-3a,6a,7,7a-tetrahydro-3H-cyclopenta[a]pentalene

Cas No:114095-91-9

R&D Labs maybe for 114095-91-9

Qingdao S. H. Huanyu Imp. & Exp. Co., Ltd.

Contact:86-532-88250866

Address:Room 615, World Trade Centre Building B, Hongkong Middle Roda 6#, Qingdao, Shandong, China
Tianjin Crest Pharmaceutical R&D Co., Ltd. （Tianjin Yao Technology Development Co., Ltd.）(expird)

Contact:+86-22-66211386

Address:Building B5-405, No, 80 4th Avenue, TEDA, Tianjin, China P.R. 300457
Changzhou BaoKang Pharmaceutical & Chemical Co., Ltd

Contact:(86) 519-88782201 88784080 88785278

Address:Henglin town, changzhou,Jiangsu
Hubei Lingsheng Pharmaceuticals Co., Ltd.

Contact:+86-0710-3538058

Address:Xiangyang City Xiangcheng Economic Development Zone, Hubei Province
Jiangsu Allyrise Pharmaceutical Co., Ltd.(expird)

Contact:+86-523-86818997

Address:Taizhou,Jiangsu Province,CHINA

Relevant to this article

Facile and selective procedure for the synthesis of bridged 1,2,4,5-tetraoxanes; Strong Acids As Cosolvents and catalysts for addition of hydrogen peroxide to β-diketones

Doi:10.1021/jo900226b
(2009)
Reaction of organometallic reagents with 2'- and 3'-ketouridine derivatives: Synthesis of uracil nucleosides branched at the 2'- and 3'-positions

Doi:10.1248/cpb.35.2605
(1987)
Doi:10.1039/jr9510002071
(1951)
Synthesis of new cycloalkenyliden-pyrroles by domino reaction

Doi:10.1016/j.tet.2009.01.040
(2009)
Efficient and convenient methods for synthesis of some phthalazine derivatives and their evaluation of cytotoxicity

Doi:10.1080/00397911.2013.837486
(2014)
η-(Benzene)bis(trimethylphosphin)iron: A Useful Precursor to Polyene Iron Derivatives. Crystal Stucture of 2-4-η-1,1'-bi(cyclohex-3-en-2-yl)bis(trimethylphosphine)iron(II)

Doi:10.1039/DT9870002031
(1987)

Article Doi