PREPARATION OF THERMODINAMICALLY STABLE ENOL SILYL ETHERS OF γ,δ-UNSATURATED KETONES BY PALLADIUM-CATALYZED DECARBOXYLATION-ALLYLATION OF ALLYL 2,3-DISUBSTITUTED 3-TRIMETHYLSILOXYACRYLATES

DOI: 10.1016/S0040-4039(00)96134-3

Source and publish data:

Tetrahedron Letters p. 2397 - 2398 (1987)

Update date:2022-08-02

Topics: γ,δ-UNSATURATED KETONES

Authors:

Tsuji, Jiro

Ohashi, Yukihiro

Minami, Ichiro

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Article abstract of DOI:10.1016/S0040-4039(00)96134-3

Allyl 2,3-disubstituted 3-trimethylsiloxyacrylates underwent palladium-catalyzed intramolecular decarboxylation-allylation to afford enol silyl ethers of γ,δ-unsaturated ketones.

Full text of DOI:10.1016/S0040-4039(00)96134-3

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