Journal of Organic Chemistry p. 2925 - 2937 (1988)
Update date:2022-08-05
Topics:
Soederberg, Bjoern
Akermark, Bjoern
Hall, Stan S.
1,4-Cyclohexadienes in the presence of bis(acetonitrile)palladium dichloride in methanol are stereoselectively converted to trans-bis(5-methoxy-1-3-η3-cyclohexenyl)palladium chloride complexes.A series of substituted 1,4-cyclohexadienes was studied to determine the effects of substituents.Subsequent methoxycarbonylation regioselectively and stereoselectivity afforded the corresponding methyl trans-5-methoxy-2-cyclohexene-1-carboxylates.The two-reaction sequence can be coupled in a tandem reaction procedure.
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(1988)