ε2-Coordination in pentacoordinate iron complexes

DOI: 10.1016/0022-328X(89)87232-8

Source and publish data:

Journal of Organometallic Chemistry p. 397 - 410 (1989)

Update date:2022-09-26

Topics: Ligand Complexes Coordination Experimental Iron complexes Pentacoordinate

Authors:

Birk, Reiner

Berke, Heinz

Hund, Hans-Ulrich

Huttner, Gottfried

Zsolnai, Laszlo

et al. et al.

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Article abstract of DOI:10.1016/0022-328X(89)87232-8

The reactions of the dinitrogen complexes μ-N22 (L = P(OMe)3 1a; P(O-i-Pr)3, 1b; PEt3, 1c with diphenylketene diphenyl-p-tolylketene imine and propionitrile give the η²-C,O ketene compounds Fe(CO)2L2Ph2C2O (L = P(OMe)3, 2a; P(O-i-Pr)3, 2b; PEt3, 2c) a ketene imine system Fe(CO)22Ph2C2N-p-tolyl (3 and the propionitrile substitution derivatives Fe(CO)2L2EtCN (L = P(OMe)3 4; PEt3, 5), respectively.The structures of 2c, 3 and 5a have been determined by X-ray diffraction.

Full text of DOI:10.1016/0022-328X(89)87232-8

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