Scholarly article on ((C5H4N)2)NiN(C6H5)C(O)CH2CH(CH2CH2CHCH2) 114571-96-9 from Journal of Organometallic Chemistry p. 403 - 412

DOI: 10.1016/0022-328X(87)80256-5

Source and publish data:

Journal of Organometallic Chemistry p. 403 - 412 (1987)

Update date:2022-08-04

Topics:

Authors:

Hernandez, Elisa

Hoberg, Heinz

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(87)80256-5

Phenyl isocyanate reacts readily with 1,5-hexadiene and a (ligand)nickel(0) system forming two regioisomeric azanickela-five ring complexes by 1 1 CC-coupling at -10°C. On warming, subsequent reactions eventually yield five-membered carbocyclic amides by intramolecular cyclisation. It has been found that by using a special experimental procedure - continuous slow addition of the isocyanate to a solution containing the diene and nickel(0) complexes - the reaction can be carried out catalytically. With this approach, 1,6-heptadiene gives both a carbocyclic and an acyclic amide. The catalytic cycles are presented and discussed in detail.

Full text of DOI:10.1016/0022-328X(87)80256-5

Products guided by the article

Product name:((C₅H₄N)2)NiN(C₆H₅)C(O)CH₂CH(CH₂CH₂CHCH₂)

Cas No:114571-96-9

R&D Labs maybe for 114571-96-9

SHAANXI TOP PHARM CHEMICAL CO.LTD

Contact:+86-029-85733403

Address:No.108 ,west sector,south er huan,xi'an,china
Wuhan Fortuna Chemical Co.,Ltd

website:http://www.fortunachem.com

Contact:86-27-59207850

Address:Add: Room 2015, No.2 Building, Kaixin Mansion No.107 Jinqiao Avenue, Wuhan, China
Weifang Yukai Chemical Co.,Ltd.

website:http://www.yukaichem.com/en.html

Contact:+86-536-8865336

Address:binhai economic development zone，262737 shangdong，china
Lonzeal Pharmaceuticals Co., Ltd.

website:http://www.lonzeal.com

Contact:+86-13381011962

Address:RM 801, Yue MOMA, No. 26 Anningzhuang Rd. Haidian District, Beijing, China
Huzhou City Linghu Xinwang Chemical Co.,Ltd.

Contact:86-572-3948695/3945236

Address:huzhou

Relevant to this article

Photoreversible Zn²⁺ ion transportation across an interface using ion-chelating substituted photochromic 3,3′-indolospirobenzopyrans: Steric and electronic controlling effects

Doi:10.1002/ejic.200800614
(2008)
Synthesis of sulfoximine-derived P,N ligands and their applications in asymmetric quinoline hydrogenations

Doi:10.1002/adsc.200800068
(2008)
An efficient synthesis of dihydrothiophene ureidoformamides by domino reactions of 1,3-thiazolidinedione under catalyst-free conditions

Doi:10.1039/c0gc00884b
(2011)
Synthesis, characterization and antimicrobial studies on some newer imidazole analogs

Doi:10.3797/scipharm.0803-04
(2008)
Discovery and evaluation of BMS-708163, a potent, selective and orally bioavailable γ-secretase inhibitor

Doi:10.1021/ml1000239
(2010)
Crystal structure and characterization of a double-helical-chain coordination polymer zinc complex constructed by flexible dicarboxylate ligand 2-nitrobenzene-1,4-di(oxyacetate) and rigid 2,2′-bipyridine ligand

Doi:10.1002/zaac.200700490
(2008)

Article Doi

DOI: 10.1016/0022-328X(87)80256-5