Scholarly article on ((C5H4N)2)NiN(C6H5)C(O)CH2CH(CH2CH2CHCH2) 114571-96-9 from Journal of Organometallic Chemistry p. 403 - 412

DOI: 10.1016/0022-328X(87)80256-5

Source and publish data:

Journal of Organometallic Chemistry p. 403 - 412 (1987)

Update date:2022-08-04

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Authors:

Hernandez, Elisa

Hoberg, Heinz

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Article abstract of DOI:10.1016/0022-328X(87)80256-5

Phenyl isocyanate reacts readily with 1,5-hexadiene and a (ligand)nickel(0) system forming two regioisomeric azanickela-five ring complexes by 1 1 CC-coupling at -10°C. On warming, subsequent reactions eventually yield five-membered carbocyclic amides by intramolecular cyclisation. It has been found that by using a special experimental procedure - continuous slow addition of the isocyanate to a solution containing the diene and nickel(0) complexes - the reaction can be carried out catalytically. With this approach, 1,6-heptadiene gives both a carbocyclic and an acyclic amide. The catalytic cycles are presented and discussed in detail.

Full text of DOI:10.1016/0022-328X(87)80256-5

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Product name:((C₅H₄N)2)NiN(C₆H₅)C(O)CH₂CH(CH₂CH₂CHCH₂)

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DOI: 10.1016/0022-328X(87)80256-5