MECHANISTIC ASPECTS OF FLUORIDE ION-CATALYZED REDUCTION OF CARBONYL COMPOUNDS WITH HYDROSILANES

DOI: 10.1016/S0040-4039(00)96096-9

Source and publish data:

Tetrahedron Letters p. 2263 - 2264 (1987)

Update date:2022-08-04

Topics:

Authors:

Fujita, Makoto

Hiyama, Tamejiro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)96096-9

Fluoride ion catalyzed reduction of aldehydes and ketones with hydrosilane in HMPA is found to involve a hexavalent silicate (1-) as the active hydride species, and no evidence is obtained for interaction of the carbonyl oxygen with the silic

Full text of DOI:10.1016/S0040-4039(00)96096-9

Products guided by the article

Product name:(cyclohexylmethoxy)dimethyl-p-tolylsilane

Cas No:114660-36-5

R&D Labs maybe for 114660-36-5

Shanghai Rich Chemicals Co., Ltd

website:http://www.richchemical.com

Contact:+86-21-20255798

Address:Pudong Shanghai,China
Hunan Haili Chemical Industry Co.,Ltd.

Contact:+86-731-85521860

Address:No.251, 2nd Section, Furong Road, Changsha,Hunan,China
Shanghai Forever Biotech Co., Ltd.

Contact:+86-21-69734790

Address:Room 5017/5019、5022、5024 of Technology Innovation Centre, No.1155, Gongyuan East Rd, QingPu District, Shanghai China.
Sarchem Laboratories, Inc.

Contact:732.938.2777

Address:5012 Industrial Road Farmingdale, NJ 07727
Shenyang Xinyihan Chemical Technology Co., Ltd.

Contact:+86-18525026267

Address:362, aigongbeijei street 23 , tiexi district,Shenyang, Liaoning, China

Relevant to this article

Doi:10.1021/ja01525a041
(1959)
DIFFERENT SELECTIVITIES IN BROMOFLUORINATION REACTIONS USING N-BROMOSUCCINIMIDE/ TRIETHYLAMINE TRIS HYDROFLUORIDE OR OLAH'S REAGENT

Doi:10.1016/S0040-4039(00)84975-8
(1986)
FORMATION OF A DIPOLAR ADDUCT IN THE REACTION OF ARYLCHLOROCARBENES WITH DIETHYL MALEATE

Doi:10.1016/S0040-4039(00)84961-8
(1986)
CeCl₃·7H₂O-catalyzed synthesis of 1-oxo-hexahydroxanthene derivatives in aqueous media

Doi:10.1080/00397910802154253
(2008)
SYNTHETIC RECEPTOR ANALOGUES: PREPARATION OF THE 3-O-METHYL, 3-C-METHYL, AND 3-DEOXY DERIVATIVES OF METHYL 4-O-α-D-GALACTOPYRANOSYL-β-D-GALACTOPYRANOSIDE (METHYL β-D-GALABIOSIDE)

Doi:10.1016/S0008-6215(00)90292-1
(1986)
A NEW PYRIDINE SYNTHESIS STARTING FROM α, β-UNSATURATED CARBONYL COMPOUNDS

Doi:10.1016/S0040-4039(00)83901-5
(1986)

Article Doi