MECHANISTIC ASPECTS OF FLUORIDE ION-CATALYZED REDUCTION OF CARBONYL COMPOUNDS WITH HYDROSILANES

DOI: 10.1016/S0040-4039(00)96096-9

Source and publish data:

Tetrahedron Letters p. 2263 - 2264 (1987)

Update date:2022-08-04

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Authors:

Fujita, Makoto

Hiyama, Tamejiro

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Article abstract of DOI:10.1016/S0040-4039(00)96096-9

Fluoride ion catalyzed reduction of aldehydes and ketones with hydrosilane in HMPA is found to involve a hexavalent silicate (1-) as the active hydride species, and no evidence is obtained for interaction of the carbonyl oxygen with the silic

Full text of DOI:10.1016/S0040-4039(00)96096-9

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