Bromination of Molybdenum Carbonyls revisited: Oxo Complexes and Routes toNew Materials Chemistry

DOI: 10.1039/DT9950001489

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1489 - 1496 (1995)

Update date:2022-08-04

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Authors:

Backhouse, James R.

Lowe, Helen M.

Sinn, Ekkehard

Suzuki, Shigeru

Woodward, Simon

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Article abstract of DOI:10.1039/DT9950001489

The use of in situ <2> led to considerably improved preparations of for which the rate of decarbonylation to is greatly increased by refluxing under reduced pressure (15-20 mmHg).Attempts to prepare 2> by Br2 addition to cis- or trans-2> led to .The OP(C6H11)3 complex may be used as a catalyst for the epoxidation of cyclohexene or for the addition of singlet oxygen to α-terpinene (1-isopropyl-4-methylcyclohexa-1,3-diene).The species > was adsorbed onto sodium montmorillonite in a new type of reaction for sodium montmorillonite involving multiple abstractions of NaBr from the complex anion.In solution > also decomposes to crystalline 2> which is monoclinic, space group C2/c .

Full text of DOI:10.1039/DT9950001489

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