Bromination of Molybdenum Carbonyls revisited: Oxo Complexes and Routes toNew Materials Chemistry

DOI: 10.1039/DT9950001489

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1489 - 1496 (1995)

Update date:2022-08-04

Topics:

Authors:

Backhouse, James R.

Lowe, Helen M.

Sinn, Ekkehard

Suzuki, Shigeru

Woodward, Simon

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9950001489

The use of in situ <2> led to considerably improved preparations of for which the rate of decarbonylation to is greatly increased by refluxing under reduced pressure (15-20 mmHg).Attempts to prepare 2> by Br2 addition to cis- or trans-2> led to .The OP(C6H11)3 complex may be used as a catalyst for the epoxidation of cyclohexene or for the addition of singlet oxygen to α-terpinene (1-isopropyl-4-methylcyclohexa-1,3-diene).The species > was adsorbed onto sodium montmorillonite in a new type of reaction for sodium montmorillonite involving multiple abstractions of NaBr from the complex anion.In solution > also decomposes to crystalline 2> which is monoclinic, space group C2/c .

Full text of DOI:10.1039/DT9950001489

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Mo(CO)2(triphenylphosphane)2Br₂

Cas No:114673-03-9

R&D Labs maybe for 114673-03-9

Taizhou volsen chemical Co., Ltd

website:http://www.volsenchem.com

Contact:+86-576-88869393

Address:Jiaojiang District, Taizhou, Zhejiang, China.
Huaian Double Win Chemicals Co.,Ltd.

Contact:+86-13511538872

Address:Blk 43,Greenland Century Town,Huaian District, Huaian City,Jiangsu Province,China
HANWAYS CHEMPHARM CO.,LIMITED

website:http://www.hanwayschem.com

Contact:+86-18502787239(whatsapp)-

Address:18-1-802, Green Garden, Jianghan District, Wuhan 430023, China
Arromax Pharmatech Co.,Ltd

website:http://www.arromax.com

Contact:+86-0512-62959601 skype:aimmezhang

Address:Suite 401, Bldg A3, 218 Xinghu St.Suzhou Industrial Park 215123, P.R. China
Lishui Nanming Chemical Co., Ltd(expird)

Contact:+86-0578-2134101，2697830

Address:No.19 Tongji Road Shuige Industrial zone

Relevant to this article

Carbon-7 Substituted Actinomycin D Analogues as Improved Antitumor Agents: Synthesis and DNA-Binding and Biological Properties

Doi:10.1021/jm00352a023
(1982)
Dda helicase unwinds a DNA-PNA chimeric substrate: Evidence for an inchworm mechanism

Doi:10.1016/j.bmcl.2006.01.013
(2006)
UEBERGANGSMETALL-HETEROALLEN-KOMPLEXE XVII. REAKTIONEN DES AZA-ALLYL-KOMPLEXES (KETENIMIN)Fe2(CO)6 MIT PHOSPHANEN

Doi:10.1016/0022-328X(87)80230-9
(1987)
Copper-catalyzed synthesis of β-haloalkenyl chalcogenides by addition of dichalcogenides to internal alkynes and its application to synthesis of (Z)-tamoxifen

Doi:10.1016/j.tet.2009.01.094
(2009)
Two titanium-catalyzed reaction sequences for syntheses of pyrroles from(E/Z)-Chloroenynes or α-Haloalkynols

Doi:10.1021/ol900522g
(2009)
New indole-containing luminophores: Convenient synthesis and aggregation- induced emission enhancement

Doi:10.1002/poc.1461
(2009)

Article Doi