Welcome to LookChem.com Sign In|Join Free

Article Doi

Bromination of Molybdenum Carbonyls revisited: Oxo Complexes and Routes toNew Materials Chemistry

DOI: 10.1039/DT9950001489

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1489 - 1496 (1995)

Update date:2022-08-04

Topics:

Authors:

Backhouse, James R.Backhouse, James R.

Lowe, Helen M.Lowe, Helen M.

Sinn, EkkehardSinn, Ekkehard

Suzuki, ShigeruSuzuki, Shigeru

Woodward, SimonWoodward, Simon

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9950001489

The use of in situ <2> led to considerably improved preparations of for which the rate of decarbonylation to is greatly increased by refluxing under reduced pressure (15-20 mmHg).Attempts to prepare 2> by Br2 addition to cis- or trans-2> led to .The OP(C6H11)3 complex may be used as a catalyst for the epoxidation of cyclohexene or for the addition of singlet oxygen to α-terpinene (1-isopropyl-4-methylcyclohexa-1,3-diene).The species > was adsorbed onto sodium montmorillonite in a new type of reaction for sodium montmorillonite involving multiple abstractions of NaBr from the complex anion.In solution > also decomposes to crystalline 2> which is monoclinic, space group C2/c .

View More

Products guided by the article

Product name:Mo(CO)2(triphenylphosphane)2Br2

Cas No:114673-03-9

114673-03-9

R&D Labs maybe for 114673-03-9

Relevant to this article

Hot Product