Biohydrogenation of Unsaturated Compounds by Saccharomyces cerevisiae. Part 2. (S)-(-)-Ethyl 4-Hydroxy-3-methylbutenoate as a Chiral Synthon for the Preparation of (25S)-26-Hydroxycholesterol

DOI: 10.1039/P19870001749

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 1749 - 1752 (1987)

Update date:2022-07-29

Topics:

Authors:

Ferraboschi, Patrizia

Fiecchi, Alberto

Grisenti, Paride

Santaniello, Enzo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/P19870001749

(25S)-26-Hydroxycholesterol (1b) has been synthesized from stigmasterol (4a) and (S)-(-)-ethyl 4-hydroxy-3-methylbutanoate (2a), the latter having the necessary chirality for the synthesis of the steroidal side-chain.

Full text of DOI:10.1039/P19870001749

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:(S)-1-ethoxymethoxy-2-methyl-4-phenylthiobutane

Cas No:114683-24-8

R&D Labs maybe for 114683-24-8

Jiangsu Haian Petro chemical Plant

Contact:+86-513-88902723

Address:99, Changjiang West Road, Haian County, Jiangsu
Langchem

Contact:+86+21-58956006 15800617331

Address:402 Room, 150# Cailun Road, Zhangjiang high tech park, Shanghai
Guangzhou Reachin Chemical Co., Ltd

Contact:+86-20-37087379 ext.604

Address:A122C-1, Tianyuan Plaza, 401 Tianyuan Rd., Tianhe, Guangzhou, China
GLD peptide scientific lnc.

Contact:21-7631221 15884421033

Address:326 Science and technology,Shanghai,China
Shanghai Harvest Chemical Ind. Co., Ltd.

Contact:021-51385350

Address:ROOM 806-807, AI LI CHEN BUILDING, No.333 JINGXIANG ROAD, PUDONG DISTRICT, 201206, SHANGHAI

Relevant to this article

Alkoxy-substituted derivatives of π-conjugated acyclic anion receptors: Effects of substituted positions

Doi:10.1246/cl.2009.208
(2009)
Doi:10.1021/jo01213a006
(1939)
A CONVENIENT SYNTHESIS OF C-α-D-RIBOFURANOSYL COMPOUNDS FROM 1-O-ACETYL-2,3,5-TRI-O-BENZYL-β-D-RIBOSE BY THE PROMOTION OF TRIPHENYLMETHYL PERCHLORATE

Doi:10.1016/S0008-6215(00)90880-2
(1987)
Trapping of Three-Center Ir-Sn-X Intermediates in the Reaction of Ir^I(COD) with Organotin(IV) Halides. X-ray Structure of <2-(Me2NCH2)C6H4>(COD)Ir(Br)SnMe2Br

Doi:10.1021/ja00224a021
(1988)
Self-assembly of fivefold-symmetric molecules on a threefold-symmetric surface

Doi:10.1002/anie.200805689
(2009)
Doi:10.1039/jr9560004814
(1956)

Article Doi