Biohydrogenation of Unsaturated Compounds by Saccharomyces cerevisiae. Part 2. (S)-(-)-Ethyl 4-Hydroxy-3-methylbutenoate as a Chiral Synthon for the Preparation of (25S)-26-Hydroxycholesterol

DOI: 10.1039/P19870001749

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 1749 - 1752 (1987)

Update date:2022-07-29

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Authors:

Ferraboschi, Patrizia

Fiecchi, Alberto

Grisenti, Paride

Santaniello, Enzo

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Article abstract of DOI:10.1039/P19870001749

(25S)-26-Hydroxycholesterol (1b) has been synthesized from stigmasterol (4a) and (S)-(-)-ethyl 4-hydroxy-3-methylbutanoate (2a), the latter having the necessary chirality for the synthesis of the steroidal side-chain.

Full text of DOI:10.1039/P19870001749

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