STEREOSELECTIVITY OF THE REACTION BETWEEN 7-OXABICYCLOHEPT-5-EN-2-ONE AND ORGANOCUPRATE REAGENTS

DOI: 10.1016/S0040-4039(00)96776-5

Source and publish data:

Tetrahedron Letters p. 5547 - 5548 (1987)

Update date:2022-08-04

Topics:

Authors:

Arjona, Odon

Pradilla, Roberto Fernandez de la

Manzano, Cristina

Perez, Sonia

Plumet, Joaquin

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Article abstract of DOI:10.1016/S0040-4039(00)96776-5

Lithium organocuprates add with high stereoselectivity to the hindered endo face of the carbonyl group of 7-oxabicyclo<2.2.1>hept-5-en-2-one to yield the corresponding exo alcohols.

Full text of DOI:10.1016/S0040-4039(00)96776-5

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Product name:2-exo-phenyl-7-oxabicyclo<2.2.1.>hept-5-en-2-endo-ol

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