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Nucleophilic and Electrophilic Mercaptanylations via 2-(Trimethylsilyl)ethanethiol-Derived Reagents

DOI: 10.1021/jo00248a045

Source and publish data:

Journal of Organic Chemistry p. 3125 - 3127 (1988)

Update date:2022-08-03

Topics:

Authors:

Anderson, M.B.Anderson, M.B.

Ranasinghe, M.G.Ranasinghe, M.G.

Palmer, J.T.Palmer, J.T.

Fuchs, P.L.Fuchs, P.L.

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Article abstract of DOI:10.1021/jo00248a045

2-(Trimethylsilyl)ethanethiol reacts with carboxylic acids, alkyl halides, epoxides, and enones to provide acyl- and alkyl-substituted 2-(trimethylsilyl)ethyl sulfides.Electrophilic mercaptanylation is effected by a thiol-sulfonate reagent derived from 2-(trimethylsilyl)ethanethiol.

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Full text of DOI:10.1021/jo00248a045

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Cas No:114764-22-6

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