Total synthesis of specionin - natural product or artifact ?

DOI: 10.1016/S0040-4039(00)96648-6

Source and publish data:

Tetrahedron Letters p. 4871 - 4874 (1987)

Update date:2022-09-26

Topics:

Authors:

Hussain, Nigel

Leonard, John

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Article abstract of DOI:10.1016/S0040-4039(00)96648-6

The iridoid insect antifeedant specionin has been synthesised from endo-cis-bicyclo[3.3.0]oct-7-en-2-ol. When the bis acetal ring is cyclised at a late stage the correct stereochemistry is generated selectively.

Full text of DOI:10.1016/S0040-4039(00)96648-6

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