Behavior of Carbonyl Ylide Generated from 3-Chloro-3-(p-nitrophenyl)diazirine and Acetone. 1,3-Dipolar Cycloaddition to Benzaldehyde and Epoxide Formation

DOI: 10.1246/cl.1987.2135

Source and publish data:

Chemistry Letters p. 2135 - 2138 (1987)

Update date:2022-08-03

Topics:

Authors:

Ibata, Toshikazu

Toyoda, Jiro

Liu, Michael T. H.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1987.2135

A carbonyl ylide generated from 3-chloro-3-(p-nitrophenyl)diazirine and acetone either 1,3-dipolar cycloadds to benzaldehydes to afford 2,2-dimethyl-4-aryl-5-(p-nitrophenyl)dioxole or intramolecularly cyclizes to give 2-chloro-2-methyl-3-(p-nitrophenyl)-3

Full text of DOI:10.1246/cl.1987.2135

Products guided by the article

Product name:2,2-Dimethyl-4-(4-nitro-phenyl)-5-p-tolyl-[1,3]dioxole

Cas No:115107-32-9

R&D Labs maybe for 115107-32-9

Dalian Synco Chemical Co., Ltd.

Contact:+86-411-83635150

Address:Rm 1004, 24, Tangshan Street, Dalian
jiangsu hualin chemical co.,ltd.

Contact:86-25-87787402

Address:jaingsu,china
Tianjin Pharmacn Medical Technology Co.,Ltd.

Contact:86-22-60122566ext.866(English),23359620

Address:Green Industrial Base, 6 Haitaifazhan Sixth Rd., Huayuan Industrial Area, Tianjin, 300384, China
Antaeus Bio-technology Co., LTD(expird)

Contact:021-31252569

Address:shanghai pudong
Hebei Think-Do Environment Co., Ltd

website:http://www.thinkdo-environment.com

Contact:0311-86510809-

Address:No 6, Shilian Middle Street, Circular Chemical Industry Park

Relevant to this article

The influence of substituents at C² carbon atom of thiosemicarbazones {R(H)C²=N³-N²(H)-C ¹(=S)-N¹H₂} on their dentacy in Pt ^II/Pd^II complexes: Synthesis, spectroscopy, and crystal structures

Doi:10.1002/zaac.200700538
(2008)
Modified low molecular weight cyclic peptides as mimetics of BDNF with improved potency, proteolytic stability and transmembrane passage in vitro

Doi:10.1016/j.bmc.2009.02.053
(2009)
Synthesis and Fungicidal Activity of Simple Structural 1,3-Thiazolidine-2-Thione Derivatives

Doi:10.1080/10426507.2014.931399
(2015)
The reactivity of a terminal phosphinidene complex toward styrenes

Doi:10.1021/om00098a032
(1988)
Structure-activity relationships for binding of 4-substituted triazole-phenols to macrophage migration inhibitory factor (MIF)

Doi:10.1016/j.ejmech.2019.111849
(2020)
Intramolecular nucleophilic displacement of halogen by phosphinate and thiophosphinate anions: Relative rates of formation of five- And six-membered rings 1

Doi:10.1039/a900623k
(1999)

Article Doi