Behavior of Carbonyl Ylide Generated from 3-Chloro-3-(p-nitrophenyl)diazirine and Acetone. 1,3-Dipolar Cycloaddition to Benzaldehyde and Epoxide Formation

DOI: 10.1246/cl.1987.2135

Source and publish data:

Chemistry Letters p. 2135 - 2138 (1987)

Update date:2022-08-03

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Authors:

Ibata, Toshikazu

Toyoda, Jiro

Liu, Michael T. H.

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Article abstract of DOI:10.1246/cl.1987.2135

A carbonyl ylide generated from 3-chloro-3-(p-nitrophenyl)diazirine and acetone either 1,3-dipolar cycloadds to benzaldehydes to afford 2,2-dimethyl-4-aryl-5-(p-nitrophenyl)dioxole or intramolecularly cyclizes to give 2-chloro-2-methyl-3-(p-nitrophenyl)-3

Full text of DOI:10.1246/cl.1987.2135

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