Organometallics p. 1875 - 1876 (1988)
Update date:2022-08-03
Topics:
Lammertsma, Koop
Chand, Pooran
Yang, Suh-Wan
Hung, Jul-Te
The Hammett reaction constant for the reaction of the terminal phosphinidene complex [Ph-P=W-(CO)5], as generated from the appropriate 7-phosphanorbornadiene complex, toward styrenes is reported and compared to those of free carbenes. The mild electrophilicity supports the unencumbered carbene-like nature of the phosphinidene complex and suggests a concerted addition to olefins with a slightly polar transition state.
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