NEW APPROACHES TO SYNTHETIC RECEPTORS. STUDIES ON THE SYNTHESIS AND PROPERTIES OF MACROCYCLIC C-GLYCOSYL COMPOUNDS AS CHIRAL, WATER-SOLUBLE CYCLOPHANES

Article abstract of DOI:10.1016/S0008-6215(00)90884-X

In an approach for the preparation of macrocyclic C-glycosyl compounds, the C-glycosyl residue is synthesized by acid assisted reduction of a cyclic hemiacetal with sodium cyanoborohydride.Macrocyclic formation is effected by the reaction of a symmetrical