SYNTHESIS AND APPLICATION OF A NOVEL BISPHOSPHINE LIGAND, (-)-DIOCP, AS AN UNSYMMETRIZED DIOP TO PROVE THE GENERAL UTILITY OF NEW DESIGNING CONCEPT.

DOI: 10.1016/S0040-4039(00)96352-4

Source and publish data:

Tetrahedron Letters p. 3675 - 3678 (1987)

Update date:2022-07-29

Topics:

Authors:

Chiba, Mitsuo

Takahashi, Hitoe

Takahashi, Hisashi

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Article abstract of DOI:10.1016/S0040-4039(00)96352-4

A new chiral bisphosphine-Rh complex (DIOCP-Rh) was found to show excellent catalytic activity and good enantioselectivity for the asymmetric hydrogenation of ketopantolactone proving the general utility of new designing concept.

Full text of DOI:10.1016/S0040-4039(00)96352-4

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