Journal of Organic Chemistry p. 7752 - 7758 (1994)
Update date:2022-08-02
Topics: Synthesis Alkylation Isocyanides Cyclization Spectroscopic Analysis Free Radical Cyclization Alkenyl Alkynyl Thiolysis
Bachi, Mario D.
Balanov, Anna
Bar-Ner, Nira
Thiol-mediated free radical cyclizations of but-3-enyl and but-3-ynyl isocyanides of types 6-8 give new access to 3,5-disubstituted 2-(alkyl- and 2-(arylthio)pyrrolines 11, 12, and 18.When 2-mercaptoethanol is used with the same isocyanides the reaction r
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