Thiol-Mediated Free Radical Cyclization of Alkenyl and Alkynyl Isocyanides

DOI: 10.1021/jo00104a035

Source and publish data:

Journal of Organic Chemistry p. 7752 - 7758 (1994)

Update date:2022-08-02

Topics: Synthesis Alkylation Isocyanides Cyclization Spectroscopic Analysis Free Radical Cyclization Alkenyl Alkynyl Thiolysis

Authors:

Bachi, Mario D.

Balanov, Anna

Bar-Ner, Nira

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Article abstract of DOI:10.1021/jo00104a035

Thiol-mediated free radical cyclizations of but-3-enyl and but-3-ynyl isocyanides of types 6-8 give new access to 3,5-disubstituted 2-(alkyl- and 2-(arylthio)pyrrolines 11, 12, and 18.When 2-mercaptoethanol is used with the same isocyanides the reaction r

Full text of DOI:10.1021/jo00104a035

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