INTRAMOLECULAR REACTION OF 2-(AZIDOBUTYL)-1,4-BENZOQUINONES. UNEXPECTED REARRANGEMENT TO A FUROINDOLIZIDINE-2-ONE.

DOI: 10.1016/S0040-4039(00)96661-9

Source and publish data:

Tetrahedron Letters p. 4929 - 4932 (1987)

Update date:2022-08-02

Topics:

Authors:

Schultz, Arthur G.

McMahon, Wayne G.

Staib, Ronald R.

Kulling, Rudolph K.

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Article abstract of DOI:10.1016/S0040-4039(00)96661-9

Thermal rearrangements of 2-(azidobutyl)-1,4-benzoquinone 1 give 3 and 4, while that of 10 produces ring-contracted 12; thermolysis of 12 gives ring-expanded 15.

Full text of DOI:10.1016/S0040-4039(00)96661-9

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