STEREOSELECTIVE SYNTHESIS OF SIDE CHAIN OF GLAUCASTEROL USING PALLADIUM (0) CATALYST.

DOI: 10.1016/S0040-4020(01)87708-5

Source and publish data:

Tetrahedron p. 5315 - 5320 (1987)

Update date:2022-08-03

Topics: Stereoselective synthesis

Authors:

Genet, J. P.

Gaudin, J. M.

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Article abstract of DOI:10.1016/S0040-4020(01)87708-5

A stereoselective synthesis of glaucasterol 1 with vinylic cyclopropane on the side chain, has been developed using palladium (0) catalyst and gave complete chirality transfer from C22 of benzoate 15 to C24 of glaucasterol 1.

Full text of DOI:10.1016/S0040-4020(01)87708-5

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