Journal of Fluorine Chemistry p. 95 - 106 (1988)
Update date:2022-08-03
Topics:
Nguyen, Thoai
The generation of perfluoroalkanoyl fluorides from perfluoroalkyl ethers by Lewis acids RHOCF2RF -> FRH + RFCOF depends mainly upon the nature of the alkyl RH radical.It is necessary to use RH groups with donor character and also electrophilic groups present on the radicals can facilitate the breaking of the RH-O bond.As examples, ethers with Me3SiCH2CH2 or CH2=CH-CH2 groups allowed reactions to occur readily at room temperature or below using common Lewis acids such as ZnCl2, BF3-Et2O, AlCl3.
View MoreContact:+86-518-81061113
Address:No. 8 Lingzhou Road, Lianyungang, Jiangsu, China
Suzhou Ryan Pharmachem Technology Co.,Ltd
Contact:+86-0512-68780025
Address:B-301,No.2 Taishan Road,Suzhou New District,Jiangsu,P.R. China
Contact:+1-416-493-6870
Address:Toronto, Canada
XI'AN CHUKANG BIOTECHNOLOGY CO.,LTD
Contact:29-63685658 63685359
Address:Room 3-1202,Building 1,Oriental oasis,East of Xianning Road,Xi'an,Shaanxi 710043 P.R.China
Luojiang Chenming Biological Products Co
Contact:+86 15000297032
Address:GROUP NO.4, HE SHENG VILLAGE, PANLONG TOWN,
Doi:10.1021/jm9003818
(2009)Doi:10.1002/ejic.201100811
(2012)Doi:10.1016/j.jfluchem.2008.04.012
(2008)Doi:10.1016/S0040-4039(00)86723-4
(1988)Doi:10.3109/14756366.2015.1029470
(2016)Doi:10.1016/j.bmcl.2009.02.110
(2009)