Addition von Alkinen an die μ3-Brueckenelemente von (μ3-X)2Fe3(CO)9 (X=RP, Se, Te)

DOI: 10.1016/0022-328X(89)85181-2

Source and publish data:

Journal of Organometallic Chemistry p. 297 - 308 (1989)

Update date:2022-07-29

Topics:

Authors:

Faessler, Th

Buchholz, D.

Huttner, G.

Zsolnai, L.

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Article abstract of DOI:10.1016/0022-328X(89)85181-2

The compounds (μ₃-X)2Fe3(CO)9 (R=ⁱPr, ^tBu) add alkynes (MeCCMe, PhCCH, PhCCPh) upon photochemical activation.In the resulting products (RPCR'=CR''PR)Fe3(CO)9 (2a-f) the two phosphorous centres are bridged by the alkyne ent

Full text of DOI:10.1016/0022-328X(89)85181-2

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Product name:Fe3(CO)9(μ3-μ3-t-Bu-PCHC(Ph)P-t-Bu)

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