1,3-Migration of a Phenyl Group via a Silicocation

DOI: 10.1039/c39870001461

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1461 - 1462 (1987)

Update date:2022-07-30

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Authors:

Eaborn, Colin

Lickiss, Paul D.

Najim, Sabah T.

Stanczyk, Wlodzimierz A.

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Article abstract of DOI:10.1039/c39870001461

The reaction of (Me3Si)2C(SiMe2Ph)(SiEt2I) with AgBF4 in Et2O has been shown to give a ca. 2:3 ratio of the unrearranged (Me3Si)2C(SiMe2Ph)(SiEt2F) and the rearranged (Me3Si)2C(SiMe2F)(SiEt2Ph); the reaction is thought to proceed via a Ph-bridged cation (

Full text of DOI:10.1039/c39870001461

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