Journal of the Chemical Society. Chemical communications p. 832 - 834 (1986)
Update date:2022-08-04
Topics:
Atkinson, Robert S.
Fawcett, John
Russell, David R.
Tughan, Gary
Oxidation of the 2-substituted N-amainobenzimidazole (5) in the presence of prochiral alkenes gives aziridines stereoselectively: addition, to γ,γ-dimethyl-α-methylenebutyrlactone is stereospecific and the relative configuration of the two chiral centres in the product has been confirmed by a single crystal X-ray diffraction study and is in agreement with a transition state geometry resembling (11).
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