Journal of Organic Chemistry p. 4422 - 4425 (1988)
Update date:2022-08-03
Topics:
Ojima, Iwao
Zhang, Zhaoda
The rhodium-catalyzed hydroformylation and palladium-catalyzed hydroesteryfication of N-allylamides give isoaldehyde (1) and isoester (5), respectively, with good regioselectivity through chelation control while the rhodium- and Co2Rh2(CO)12-catalyzed reactions of an N-methallylamide give a novel double carbonylation product (10) and a pyrrolidine (11), respectively, with exellent selectivity.
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