Stereoselectivity in Electrophile-Mediated Intramolecular Cyclizations of Hept-2-enitols

DOI: 10.1021/jo00263a017

Source and publish data:

Journal of Organic Chemistry p. 346 - 359 (1989)

Update date:2022-08-03

Topics:

Authors:

Freeman, Fillmore

Robarge, Kirk D.

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Article abstract of DOI:10.1021/jo00263a017

Electrophile (dibromine, diiodine, benzeneselenenyl chloride, and mercuric acetate) mediated intramolecular cyclization of (Z)-7-O-benzyl-1,2,3-trideoxy-4,5-O-isopropylidene-D-ribo-hept-2-enitol (9) gives predominantly 2,5-anhydro-1-O-benzyl-6,7-dideoxy-6

Full text of DOI:10.1021/jo00263a017

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Product name:3,6-anhydro-7-O-benzyl-1,2-dideoxy-2-iodo-4,5-O-isopropylidene-D-glycero-D-gluco-heptitol

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