Organic Letters p. 2531 - 2534 (2009)
Update date:2022-07-29
Topics:
Takamura, Hiroyoshi
Kikuchi, Shigetoshi
Nakamura, Yuichi
Yamagami, Yuji
Kishi, Takayuki
Kadota, Isao
Yamamoto, Yoshinori
A total synthesis of brevenal is described. The pentacyclic ether core was constructed by the intramolecular allylation of α-acetoxy ether and subsequent ring - closing metathesis. Both of the diene side chains were introduced by Wittig olefination and a
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(1961)