Tetrahedron Letters p. 1283 - 1286 (1988)
Update date:2022-08-04
Topics:
Smadja, William
Stereospecifically β-deuterated acyclic α-phenylketones, namely the syn- and anti-5,5-dimethyl-3-phenylhexan-2-ones-4-d1, have been synthesized by Heck reaction using corresponding deuterium labelled E-allylic alcohols.The ketones obtained can serve for an accurate measurement of racemization of α-arylketones, using 1H and 2H NMR spectroscopy.
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