A Simple and Direct Synsthesis of α-Hydroxy Unsaturated Adehydes from α-Cyano- α-Hydroxymethyl Epoxides

DOI: 10.1039/c39870001869

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1869 - 1870 (1987)

Update date:2022-07-31

Topics:

Authors:

Khamliche, Layachi

Robert, Albert

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39870001869

The ring opening of α-cyano-α-hydroxymethyl epoxides by a solution of the complex Li2NiBr4 in the tetrahydrofuran leads to α-bromo-α'-hydroxy ketones which in treatment with pyridine give good yields of α-hydroxy unsaturated aldehydes.

Full text of DOI:10.1039/c39870001869

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:2-Propanone, 1-bromo-3-hydroxy-1-(4-nitrophenyl)-

Cas No:116204-28-5

R&D Labs maybe for 116204-28-5

Shanghai Forever Biotech Co., Ltd.

Contact:+86-21-69734790

Address:Room 5017/5019、5022、5024 of Technology Innovation Centre, No.1155, Gongyuan East Rd, QingPu District, Shanghai China.
Chengda Pharmaceuticals Co., Ltd.

Contact:+86-573-84601188

Address:hengshan Road 5# in Jiashan, zhejiang
JIAXING SUNS INTERNATIONAL TRADE CO LTD

Contact:18367306858

Address:No.123,Huixin Avenue,Huimin Dist
Jinan Kaypharm Chemical Co.,Ltd

Contact:86-0531-86986780

Address:Room101,No189-2,Huayuan Road,Jinan City,Shandong Province
ALPHA PHARMACEUTICAL CO，LTD JIANGSU

Contact:+86-527-84829968,+86-527-84829998

Address:suqian city

Relevant to this article

New naphthyridine-based bipolar host materials for thermally activated delayed fluorescent organic light-emitting diodes

Doi:10.1016/j.orgel.2019.04.003
(2019)
The effect of deoxyfluorination and: O -acylation on the cytotoxicity of N -acetyl-d-gluco- And d-galactosamine hemiacetals

Doi:10.1039/d1ob00497b
(2021)
Type III Intramolecular <2 + 2> Cycloadditions of Vinylketenes

Doi:10.1021/jo00257a022
(1988)
Chlorzoxazone esters of some non-steroidal anti-inflammatory (NSAI) carboxylic acids as mutual prodrugs: Design, synthesis, pharmacological investigations and docking studies

Doi:10.1016/j.bmc.2009.03.065
(2009)
Cascade Reaction of α, β-Unsaturated Ketones and 2-Aminoaryl Alcohols for the Synthesis of 3-Acylquinolines by a Copper Nanocatalyst

Doi:10.1002/adsc.202100631
(2021)
Chiral a-substituted allylboronates in a one-pot three-component asymmetric allylic alkylation/carbonyl allylation reaction sequence -Applications to the syntheses of (+)-(3R,5R)-3-hydroxy-5-decanolide and (-)-massoialactone

Doi:10.1139/V09-036
(2009)

Article Doi