A Simple and Direct Synsthesis of α-Hydroxy Unsaturated Adehydes from α-Cyano- α-Hydroxymethyl Epoxides

DOI: 10.1039/c39870001869

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1869 - 1870 (1987)

Update date:2022-07-31

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Authors:

Khamliche, Layachi

Robert, Albert

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Article abstract of DOI:10.1039/c39870001869

The ring opening of α-cyano-α-hydroxymethyl epoxides by a solution of the complex Li2NiBr4 in the tetrahydrofuran leads to α-bromo-α'-hydroxy ketones which in treatment with pyridine give good yields of α-hydroxy unsaturated aldehydes.

Full text of DOI:10.1039/c39870001869

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