Diastereoselective Wittig Rearrangement of Tertiary Allylic Ethers

DOI: 10.1021/jo00254a054

Source and publish data:

Journal of Organic Chemistry p. 4631 - 4633 (1988)

Update date:2022-08-05

Topics:

Authors:

Wittman, Mark D.

Kallmerten, James

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00254a054

The <2,3> Wittig rearrangement of oxazoline ethers of α-alkoxy, tertiary allylic alcohols affords a diastereoselective entry to remotely fuctionalized trisubstituted olefins; the stereochemistry of the rearrangement is directed by a stereogenic center ext

Full text of DOI:10.1021/jo00254a054

Products guided by the article

Product name:2-[(E)-(S)-1-((1S,2R)-3-Benzyloxy-1-methoxymethoxy-2-methyl-propyl)-1-methyl-but-2-enyloxymethyl]-4,4-dimethyl-4,5-dihydro-oxazole

Cas No:116233-37-5

R&D Labs maybe for 116233-37-5

KINHENG CHEMICAL(SHANGHAI)CO., LTD.

Contact:+8621-60490170

Address:Room401, No.28,Lane 189, Yangshupu Rd. Shanghai, China.
Jiangsu Hualun Chemical Industry Co., Ltd

website:http://www.hualunchem.com

Contact:+86-0514-86464168 86507985

Address:39# Middle Renmin Road, Dinghuo Town
Shanghai Egoal Chemical Co.,Ltd

Contact:+86-21-50333091

Address:Yangming Garden Square 3,YangGao North Road 1188, Pudong New District, Shanghai
HUNAN CHEMAPI BIOLOGICAL TECHNOLOGY CO.,LTD.

Contact:+86-186-02659358

Address:1004, building 3, Wanke Jinsemaitianyuan, 498 Guitang Road, Yuhua District, Changsha City, Hunan Province, China
Changzhou Hopschain Chemical Co.,Ltd

website:http://www.hopschem.cn/products.html

Contact:86-519-85528066

Address:Room 710, Unit A, Xingbei Development Mansion, Tongjiang Road, Changzhou City,213000, China

Relevant to this article

Palladium-Catalyzed Migratory Insertion of Isocyanides for Synthesis of C-Phosphonoketenimines

Doi:10.1021/acscatal.6b01253
(2016)
Application of allylboronates to the synthesis of carbomycin B

Doi:10.1021/jo00256a023
(1988)
Diphenylamine-derived bis-hydroxyamide catalyzed asymmetric borane reduction of prochiral ketones

Doi:10.1016/j.tetasy.2009.02.057
(2009)
Efficient stereoselective synthesis of nitrocyclopropanes by the oxidative cyclization of Michael adducts of nitroolefins with activated methylene compounds

Doi:10.1002/adsc.200800452
(2008)
Degradation of oleandomycin: Controlled removal of sugars to give oleandonolide C₃,C'5-acetonide

Doi:10.1016/S0040-4020(01)85115-2
(1988)
Asymmetrie allylation of methyl ketones by using chiral phenyl carbinols

Doi:10.1002/chem.200900062
(2009)

Article Doi