Diastereoselective Wittig Rearrangement of Tertiary Allylic Ethers

DOI: 10.1021/jo00254a054

Source and publish data:

Journal of Organic Chemistry p. 4631 - 4633 (1988)

Update date:2022-08-05

Topics:

Authors:

Wittman, Mark D.

Kallmerten, James

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00254a054

The <2,3> Wittig rearrangement of oxazoline ethers of α-alkoxy, tertiary allylic alcohols affords a diastereoselective entry to remotely fuctionalized trisubstituted olefins; the stereochemistry of the rearrangement is directed by a stereogenic center ext

Full text of DOI:10.1021/jo00254a054

Products guided by the article

Product name:2-[(E)-(S)-1-((1S,2R)-3-Benzyloxy-1-methoxymethoxy-2-methyl-propyl)-1-methyl-but-2-enyloxymethyl]-4,4-dimethyl-4,5-dihydro-oxazole

Cas No:116233-37-5

R&D Labs maybe for 116233-37-5

Suqian Ruixing Chemical Co., Ltd.

Contact:+86-527-80805666（总机）;84836008(销售)

Address:3 Jingsilu, Zone north, Hubin Xincheng Development Park, Suqian, China
LINYI FUDE FINE CHEMICAL CO.,LTD

Contact:86-539-2361184

Address:YISHUI, LINYI,SAHNDONG,CHINA
QINGDAO HONG JIN CHEMICAL CO.,LTD.

website:http://www.hongjinchem.com

Contact:+86-532-83657313

Address:2ND Building, 8 Shangqing Road, Qingdao, Shandong Province, China.
Shanghai Kefu Chemical Co.,Ltd.

Contact:+86-21-34616196

Address:Room601-602, Xuhui Business Building, No.168, Yude Road, Shanghai
Huaian Double Win Chemicals Co.,Ltd.

Contact:+86-13511538872

Address:Blk 43,Greenland Century Town,Huaian District, Huaian City,Jiangsu Province,China

Relevant to this article

Palladium-Catalyzed Migratory Insertion of Isocyanides for Synthesis of C-Phosphonoketenimines

Doi:10.1021/acscatal.6b01253
(2016)
Application of allylboronates to the synthesis of carbomycin B

Doi:10.1021/jo00256a023
(1988)
Diphenylamine-derived bis-hydroxyamide catalyzed asymmetric borane reduction of prochiral ketones

Doi:10.1016/j.tetasy.2009.02.057
(2009)
Efficient stereoselective synthesis of nitrocyclopropanes by the oxidative cyclization of Michael adducts of nitroolefins with activated methylene compounds

Doi:10.1002/adsc.200800452
(2008)
Degradation of oleandomycin: Controlled removal of sugars to give oleandonolide C₃,C'5-acetonide

Doi:10.1016/S0040-4020(01)85115-2
(1988)
Asymmetrie allylation of methyl ketones by using chiral phenyl carbinols

Doi:10.1002/chem.200900062
(2009)

Article Doi