The Case Favoring Direct C-Alkylation of Heteroatom-Substituted Enolates

DOI: 10.1021/jo00256a029

Source and publish data:

Journal of Organic Chemistry p. 5058 - 5062 (1988)

Update date:2022-08-05

Topics:

Authors:

Solomon, Mark

Hoekstra, William

Zima, George

Liotta, Dennis

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00256a029

The alkylation of selenium-stabilized enolates has been shown to proceed by direct alkylation of the enolate carbon atom, rather than by alkylation on selenium and subsequent alkyl group migration to carbon.

Full text of DOI:10.1021/jo00256a029

Products guided by the article

Product name:2-Benzyl-2-(3-methyl-but-2-enylselanyl)-3,4-dihydro-2H-naphthalen-1-one

Cas No:116279-51-7

R&D Labs maybe for 116279-51-7

Shanghai Zhihua ChemTech Co., Ltd.

Contact:+86-13774313779

Address:Room 817 Suite B 3333 Shenjiang Road
Shanghai Bocimed Pharmaceutical Co., Ltd.

website:http://www.bocimed.com

Contact:+86-21-68861632

Address:Building 1, Lane 647, Songtao Road, Zhangjiang High-Tech Park, Shanghai
Hangzhou Mole's Science & Technology Co.,Ltd.(expird)

Contact:+86-571-56880228

Address:15F Guodu development Building, NO.182 Zhaohui Road
Huangshi Meifeng Chemical Co.,ltd.

Contact:+86-714-6516706

Address:1941-4-3#,Hubin Avenue,Huangshi,Hubei,China
ShenZhen InnoSyn Biotech Co.,Ltd

website:http://www.innosyns.com

Contact:+86-755-28351685

Address:Floor 5 & 6, Building A1, HAIKEXING Strategic Innovative Industrial Park, 16 BaoShan Road, PingShan District

Relevant to this article

A NOVEL STEREOSPECIFIC RADICAL CYCLIZATION OF 2',3'-O-ISOPROPYLIDENEURIDE AND -ADENOSINE 5'-ALDEHYDE TO THE CORRESPONDING 6,5'-CYCLODIHYDROURIDINE AND 8,5'-CYCLOADENOSINE DERIVATES

Doi:10.1016/0040-4039(88)80020-0
(1988)
Toward biophysical probes for the 5-HT₃ receptor: Structure-activity relationship study of granisetron derivatives

Doi:10.1021/jm901827x
(2010)
PHOTOPHYSICS AND PHOTOCHEMISTRY OF P-BENZOYLPHENYLDIPHENYLMETHYL IN SOLUTION

Doi:10.1016/S0040-4039(00)80692-9
(1988)
N-Azamonobactams. 2. Synthesis of Some N-Iminoacetic Acid and N-Glycyl Analogues

Doi:10.1021/jm00128a014
(1989)
Tris(t-butyldimethylsilyl)trimethylsilylethylene and Tetrakis(dimethylsilyl)ethylene. The Most Twisted and Untwisted Tetrasilylethylenes

Doi:10.1246/cl.1988.965
(1988)
Synthesis of bicyclic ethers by a gold/palladium/gold-catalyzed cyclization/cross coupling sequence

Doi:10.1002/ejoc.200901010
(2010)

Article Doi