The Case Favoring Direct C-Alkylation of Heteroatom-Substituted Enolates

DOI: 10.1021/jo00256a029

Source and publish data:

Journal of Organic Chemistry p. 5058 - 5062 (1988)

Update date:2022-08-05

Topics:

Authors:

Solomon, Mark

Hoekstra, William

Zima, George

Liotta, Dennis

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00256a029

The alkylation of selenium-stabilized enolates has been shown to proceed by direct alkylation of the enolate carbon atom, rather than by alkylation on selenium and subsequent alkyl group migration to carbon.

Full text of DOI:10.1021/jo00256a029

Products guided by the article

Product name:2-Benzyl-2-(3-methyl-but-2-enylselanyl)-3,4-dihydro-2H-naphthalen-1-one

Cas No:116279-51-7

R&D Labs maybe for 116279-51-7

Shandong Shouguang Songchuan Industrial Additives Co.,Ltd

Contact:+86-536-8566856

Address:Shouguang,Shandong,China
Taixing Shenfeng Chemical Co., Ltd.

Contact:+86-523-87117033, 87117666

Address:4# Yinsanlu, Huangqiao town, Taixing, Jiangsu, China.
Shanghai Sunway Pharmaceutical Technology Co.,Ltd.

Contact:+86-21-5161 3915

Address:Shanghai YangPu
Zhejiang Sucon Silicone Co.,Ltd

Contact:+86-575-88046692

Address:Qisheng Rd., Paojiang Industrial Zone, Shaoxing, Zhejiang, China.
KODI CHEMICAL CO., LTD

Contact:021

Address:Pudong

Relevant to this article

A NOVEL STEREOSPECIFIC RADICAL CYCLIZATION OF 2',3'-O-ISOPROPYLIDENEURIDE AND -ADENOSINE 5'-ALDEHYDE TO THE CORRESPONDING 6,5'-CYCLODIHYDROURIDINE AND 8,5'-CYCLOADENOSINE DERIVATES

Doi:10.1016/0040-4039(88)80020-0
(1988)
Toward biophysical probes for the 5-HT₃ receptor: Structure-activity relationship study of granisetron derivatives

Doi:10.1021/jm901827x
(2010)
PHOTOPHYSICS AND PHOTOCHEMISTRY OF P-BENZOYLPHENYLDIPHENYLMETHYL IN SOLUTION

Doi:10.1016/S0040-4039(00)80692-9
(1988)
N-Azamonobactams. 2. Synthesis of Some N-Iminoacetic Acid and N-Glycyl Analogues

Doi:10.1021/jm00128a014
(1989)
Tris(t-butyldimethylsilyl)trimethylsilylethylene and Tetrakis(dimethylsilyl)ethylene. The Most Twisted and Untwisted Tetrasilylethylenes

Doi:10.1246/cl.1988.965
(1988)
Synthesis of bicyclic ethers by a gold/palladium/gold-catalyzed cyclization/cross coupling sequence

Doi:10.1002/ejoc.200901010
(2010)

Article Doi